Misc: U S President, John Quincy ________?

Questions

who appears on the us 5,000 dollar bill?

which character sang, 'when you wish upon a star..' in disney's 'pinocchio'?

who was the slavery abolitionist that was tried and hanged for his beliefs in 1859 - his name lives on in song?

which actor played "r" in the james bond movie, "the world is not enough"?

who achieved the first perfect nine innings baseball game (pitcher pitches 27 out, no hits, no runs)?